Nucleation and growth by diffusion under Ostwald-Freundlich boundary condition

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Nucleation and growth by diffusion under Ostwald-Freundlich boundary condition.

The critical radius of a nucleus grown by diffusion in a solution is studied thermodynamically as well as kinetically. The thermodynamic growth equation called Zeldovich equation of classical nucleation theory and the kinetic diffusional growth equation combined with the Ostwald-Freundlich boundary condition lead to the same critical radius. However, it should be pointed out that the diffusiona...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2014

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.4865108